4.7 Article

Crystallographic Orientation Control of 1D Sb2Se3 Nanorod Arrays for Photovoltaic Application by In Situ Back-Contact Engineering

Journal

SOLAR RRL
Volume 4, Issue 10, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/solr.202000294

Keywords

1D materials; back contacts; orientation controls; Sb(2)Se(3)nanorod arrays; solar cells

Funding

  1. National Key R&D Program of China [2019YFB1503404]
  2. Education Commission of Hebei Province [ZD2019037]
  3. National Natural Science Foundation of China (NSFC) [61804040, 11604072, U19A2092]
  4. Natural Science Foundation for Distinguished Young Scholars of Hebei Province of China [F2019201289]

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Low-dimensional (LD) crystalline inorganic semiconductors have attracted increasing interest due to their unique electrical and optical properties. The crystallographic orientation in the LD films is one of the critical parameters that determine their strong anisotropic physical properties and device performance. Antimony selenide (Sb2Se3), a 1D crystalline semiconductor, is a promising absorber material for emerging photovoltaic technologies. The suitably oriented Sb2Se3 absorbers can offer excellent carrier transport and trap-free grain boundaries, facilitating high-efficiency devices. The crystallographic orientation of the Sb2Se3 light-absorbing layer is found to be governed by the underlying layers, i.e., the back contact in substrate-type solar cells. Herein, an in situ surface selenization treatment to the tungsten (W) back contact is applied to change the growth of Sb2Se3 layer from a layer-like growth mode to an island-like growth mode. As a result, highly [hk1]-oriented Sb2Se3 nanorod arrays growing perpendicular to the W back-contact surface are achieved. Moreover, the resulting tungsten selenide (WSe2) thin layer also acts as a hole transport layer and promotes hole extraction. Consequently, a conversion efficiency as high as 8.46% in Sb2Se3 solar cells with substrate configuration is achieved.

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