Journal
ENERGY STORAGE MATERIALS
Volume 29, Issue -, Pages 300-309Publisher
ELSEVIER
DOI: 10.1016/j.ensm.2020.04.019
Keywords
Network-structured metal compound@carbon; Coupling interaction; General strategy; Alkali-metal ion battery; Fast-charging
Funding
- National Natural Science Foundation of China [51972121, 21671069]
- Guangdong Basic and Applied Basic Research Foundation [2019A1515011502]
- Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program [2017TQ04C419]
- Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme
- Program for Pearl River New Star of Science and Technology in Guangzhou [201710010104]
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Evolution of fast-charging alkali-metal ion battery (AIB) is of great importance, but severely limited by the high ion/electron transport resistance in the electrode structure. Carbon-based composites have demonstrated competitive results for accelerating the related technology development. However, their efficient design, versatile synthesis and diverse structural variability remain the major challenges. Herein, we propose a general and versatile protocol for synthesizing a hierarchical network structure composed of metal compound (e.g., metal oxide, metal selenide and metal sulfide) encapsulated in carbon nanoparticle unit, and demonstrate its superiority for fast-charging anode of AIB. Key to this strategy is utilization of a rational hybrid assembly comprising of chelating resin and metal ions as building blocks. The strong coordinate-covalent bond between chelating resin and metal ions not only realizes a highly homogeneous organic/inorganic interface at the molecular level, but also confines metal ions to in-situ generate metal compound nanoparticles uniformly distributed into the carbon framework after a carbonization treatment, endowing a strong binding at the carbon/non-carbon interface structure. Benefitting from the well-organized structure, the resultant network-structured metal compound@carbon composites exhibit extraordinary fast-charging alkali-metal ion storage performance. For example, the typical network-structured Fe2O3@carbon composite anode can be fully charged within 2.2 min and discharge continuously for more than 120 min with a large charge/discharge capacity of 730 mAh g(-1) in lithium ion batteries, and is able to be fully charged within 5.6 min accompanying with a long discharge time of about 110 min and a high charge/discharge capacity of 92 mAh g(-1) in potassium ion batteries.
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