4.0 Article

RegioselectiveBismuth-CatalyzedSynthesis of Pyranocoumarins and Furocoumarins from4-Hydroxycoumarinsand Propargyl Alcohols

Journal

BULLETIN OF THE KOREAN CHEMICAL SOCIETY
Volume 41, Issue 7, Pages 709-718

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/bkcs.12058

Keywords

Bismuth; Catalysis; Pyranocoumarin; Furocoumarin; Regioselectivity

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An efficient method for the bismuth-catalyzed regioselective synthesis of pyranocoumarins and furocoumarins has been developed from the reaction of 4-hydroxycoumarins with propargyl alcohols. The reaction proceeds through sequential propargylation and intramolecular cyclization reactions catalyzed by bismuth(III) triflate.

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