Journal
SCIENCE ADVANCES
Volume 6, Issue 25, Pages -Publisher
AMER ASSOC ADVANCEMENT SCIENCE
DOI: 10.1126/sciadv.aba3809
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Funding
- DOE/BES [DE-FG02-05ER15730]
- Advanced Photon Source at Argonne National Laboratory [DE-AC02-06CH11357]
- Center for Functional Nanomaterials, U.S. DOE Office of Science Facility, at Brookhaven National Laboratory [DE-SC0012704]
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The preferential oxidation of CO (PROX) in hydrogen-rich fuel gas streams is an attractive option to remove CO while effectively conserving energy and H-2. However, high CO conversion with concomitant high selectivity to CO2 but not H2O is challenging. Here, we report the synthesis of high-loading single Pt atom (2.0 weight %) catalysts with oxygen-bonded alkaline ions that stabilize the cationic Pt. The synthesis is performed in aqueous solution and achieves high Pt atom loadings in a single-step incipient wetness impregnation of alumina or silica. Promisingly, these catalysts have high CO PROX selectivity even at high CO conversion (similar to 99.8% conversion, 70% selectivity at 110 degrees C) and good stability under reaction conditions. These findings pave the way for the design of highly efficient single-atom catalysts, elucidate the role of -OH species in CO oxidation, and confirm the absence of a support effect for our case.
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