4.4 Article

Hydrothermal Method-Derived MnMoO4Crystals: Effect of Cationic Surfactant on Microstructures and Electrochemical Properties

Journal

CHEMISTRYSELECT
Volume 5, Issue 26, Pages 7728-7733

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/slct.202001384

Keywords

Binary transition metal oxides; Capacitive retention; Cationic surfactant

Funding

  1. MHRD RUSA-Phase 2 grant, Policy (TNMulti-Gen), Department of Education Govt. of India [24-51/2014-U]
  2. UGC-SAP
  3. DST FIST
  4. DST PURS E grant

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The development of energy devices is becoming necessary to deal with the power crisis. Binary transition manganese molybdate (MnMoO4) is considered to be a well-known material for storage applications. Electrochemical performance of anode electrode materials was tested with respect to the effect of cationic surfactant cetyltrimethylammonium bromide (C19H12BrN). The fundamental characterization studies such as X-ray diffraction, photoluminescence, Raman, and Fourier transform infrared confirmed the presence of MnMoO4. The scanning electron microscopic (SEM) images revealed well-grained micro/nanostructures. The electrochemical behavior was determined by cyclic voltammetry (CV), galvanostatic charge-discharge (GCD), and electrochemical impedance spectroscopy studies. In this study, 0.2 M CTAB/MnMoO(4)showed high 447.61 F/g specific capacitance from the CV analysis. The GCD studies showed that after 3000 cycles, the cycling stability was retained with 79.60% of capacitive retention.

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