Journal
ACS ENERGY LETTERS
Volume 5, Issue 7, Pages 2434-2443Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsenergylett.0c01010
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Funding
- National Natural Science Foundation of China (NSFC) [21825502, 51573107, 91633301, 21905185]
- Foundation of State Key Laboratory of Polymer Materials Engineering [SKLPME 2017-2-04]
- Fundamental Research Funds for the Central Universities [YJ201957]
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In this study, we report all-polymer solar cells enabled by a joint effect of p-doping and ternary blend strategies. We apply the p-doping strategy for two material systems based on a new polymer donor named PNDT-T and a conventional polymer PBDB-T. In both cases, the efficiencies are improved significantly upon the p-doping of F4-TCNQ The trace amount of F4-TCNQ contributes to the favorable trap-state filling, charge transfer, and transport but has a weaker effect on optimizing the morphology, leaving room for further improvement. Excitingly, via fabrication of the ternary blend devices based on PNDT-T-0.7:PBDB-T-0.3:DCNBT-IDT0.8 along with p-doping of F4-TCNQ in trace amounts, a significantly improved power conversion efficiency of 11.87% is realized. We find the optimized ternary blend shows high crystallinity, miscibility, and elevated phase separation comparable to those of the binary blend, thus facilitating the improved charge separation and transport.
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