4.6 Article

Study of tribological properties and lubrication mechanism of surfactant-coated anthracite sheets used as lubricant additives

Journal

FRICTION
Volume 9, Issue 3, Pages 524-537

Publisher

SPRINGER
DOI: 10.1007/s40544-019-0357-4

Keywords

anthracite; tribological properties; lubricant additive; protective film-mending effect

Funding

  1. National Natural Science Foundation of China [51373059]
  2. Science and Technology Projects in Fujian Province [2017H2001, 2018H0019, 2018H6012]
  3. Science and Technology Innovation Team of Huaqiao University [Z14X0046]
  4. Subsidized Project for Postgraduates' Innovative Fund in Scientific Research of Huaqiao University
  5. Graphene Powder & Composite Research Center, Development and Reform Commission of Fujian Province

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The span80-coated anthracite sheets showed excellent tribological properties, good dispersion stability in oil, and reduced friction coefficient, wear scar diameter, and wear volume. The combination of crystalline and amorphous carbon in anthracite sheets formed a protective film, leading to decreased wear on the friction pair, and achieving effective friction reduction and anti-wear effects in a wide range of conditions.
Anthracite sheets were coated by sorbitol fatty acid ester (span80) through ball-milling process. The tribological properties of the span80-coated anthracite sheets as the additive in polyalpha olefin were evaluated through a series of friction tests using a four ball machine. The results revealed that the span80-coated anthracite sheets exhibited excellent dispersion stability in base oil. In addition, compared with base oil, the average coefficient of friction, wear scar diameter, and wear volume of modified oil at a mass fraction of 0.03% span80-coated anthracite sheets decreased by 45.39%, 60.13%, and 95.95%, respectively. The oil containing span80-coated anthracite sheets achieved good friction-reducing and anti-wear effects over a wide range of applied loads, temperatures, or rotating speeds. Control experiments were performed as well. The results obtained using span80-coated anthracite sheets were superior to those obtained using pure anthracite. The lubrication mechanism was attributed to the synergistic action of the crystalline and amorphous carbon in anthracite sheets as they formed a protective film and played a mitigative role on the surface of friction pair, which mitigated the wear extent of the friction pair.

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