Journal
APPLIED SCIENCES-BASEL
Volume 10, Issue 16, Pages -Publisher
MDPI
DOI: 10.3390/app10165512
Keywords
cenospheres; fly ash; wet separation; chemical composition; aluminosilicate; SiO2; Al2O3; power plant
Categories
Funding
- Electricity Generating Authority of Thailand (EGAT) [59-B104000-172-IO.SS03B3008261-MTEC]
- National Metal and Materials Technology Center (MTEC) [P1651949, P1751264]
- MTEC, National Science and Technology Development Agency (NSTDA), Thailand
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The cenosphere is one becoming a focus of the power plant in terms of value addition and ash management. This study presents a systematic investigation and characterization of physical properties, morphological structures, and chemical composition of cenospheres separated from fly ash produced from the Mae Moh coal-fired power plant, Thailand. To our knowledge, this is the first report on cenospheres separation from Mae Moh class C fly ash, with high calcium content similar to 24 wt.%, by adopting the traditional wet separation method (using water as the medium) to separate the lightweight cenospheres. Various effects of process parameters (fly ash-to-water ratio, stirring method, ultrasonication, and size classification) were designed to examine the cenosphere recovery yield in comparison. The result has revealed the limit of physical stirring-settling effect associated with the cenospheres content by nature governing the percent recovery. The bulk cenospheres were subject to size sieving into different sized fractions, with the structure-chemical composition relationship established for more insight. The particle diameter/shell thickness ratio revealed its significant correlation with the aluminosilicate glass composition, with the relating cenosphere shell structures (single-ring and porous) mapped to compare for a better elucidation of their structure-property relationship. The phase composition was also studied.
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