Journal
APPLIED SCIENCES-BASEL
Volume 10, Issue 14, Pages -Publisher
MDPI
DOI: 10.3390/app10144973
Keywords
LIBS; plasma; spectroscopy; transition probabilities; oscillator strengths; Stark broadening; Stark shifts
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Funding
- Italian Ministry of Foreign Affairs and International Cooperation [MACH project-RS19GR04]
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In this review, we report and critically discuss the application of LIBS for the determination of plasma-emission fundamental parameters, such as transition probabilities, oscillator strengths, Stark broadening and shifts, of the emission lines in the spectrum. The knowledge of these parameters is of paramount importance for plasma diagnostics or for quantitative analysis using calibration-free LIBS methods. In the first part, the theoretical basis of the analysis is laid down; in the second part, the main experimental and analytical approaches for the determination by LIBS of the spectral line spectroscopic parameters are presented. In the conclusion, the future perspectives of this kind of analysis are discussed.
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