Journal
ENERGY TECHNOLOGY
Volume 8, Issue 10, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ente.202000494
Keywords
long-cycle batteries; Na3V2O2(PO4)(2)F; quasi-solid-states; sodium-ion batteries; wide temperature
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Funding
- National Natural Science Foundation of China [21773188, 21972111]
- Fundamental Research Funds for the Central Universities [XDJK2019AA002, XDJK2020C004]
- Postgraduate tutor team-building project [XYDS201911]
- China Postdoctoral Science Foundation [BX20190290, 2020M673103]
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Solid-state batteries have attracted significant attention due to their safety, but most studies focus on room-temperature performance. Herein, the electrochemical performance of quasi-solid-state sodium-ion batteries (SIBs) based on the perfluorosulfonate-based polymer electrolyte (PFSA-Na) and Na3V2O2(PO4)(2)F (NVOPF) cathode over a wide temperature range (from -25 to 65 degrees C) is investigated. The quasi-solid-state half-cells (Na//PFSA-Na//NVOPF@rGO) exhibit a long-term cycle life (88.1% capacity retention at 4 C after 1000 cycles) at room temperature. A high discharge capacity can be maintained even at a low temperature of -25 degrees C and it can be restored to the original value when the temperature increases again to 25 degrees C. Meanwhile, full-cells (hard carbon//PFSA-Na//NVOPF@rGO) can also deliver stable cycling performance in a wide temperature range (-25, 25, and 65 degrees C).
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