Journal
CATALYSTS
Volume 10, Issue 8, Pages -Publisher
MDPI
DOI: 10.3390/catal10080911
Keywords
Li-S battery; donor number; dielectric constant; polysulfides; solvent effect; DFT
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Funding
- Ministry of Science and Technology (MOST) in Taiwan [MOST 1062113-M-003-010-MY3]
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The lithium-sulfur (Li-S) battery is one of the promising energy storage alternatives because of its high theoretical capacity and energy density. Factors governing the stability of polysulfide intermediates in Li-S batteries are complex and are strongly affected by the solvent used. Herein, the polysulfide reduction and the bond cleavage reactions are calculated in different solvent environments by the density functional theory (DFT) methods. We investigate the relationship between the donor numbers (DN) as well as the dielectric constants (epsilon) of the solvent system and the relative stability of different polysulfide intermediates. Our results show that the polysulfide reduction mechanism is dominated by its tendency to form the ion-pair with Li(+)in different organic solvents.
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