4.5 Article

Facile preparation of ZnO quantum dots@porous carbon composites through direct carbonization of metal-organic complex for high-performance lithium ion batteries

Journal

CARBON LETTERS
Volume 31, Issue 2, Pages 323-329

Publisher

SPRINGER JAPAN KK
DOI: 10.1007/s42823-020-00175-5

Keywords

Zinc oxide quantum dots; Porous carbon composites; Metal-organic complex; One-step carbonization; Lithium ion battery

Funding

  1. Inha University Research Grant
  2. National Research Foundation of Korea [5199990414547] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A composite material of ZnO quantum dots (ZnO QDs) and porous carbon was prepared using a one-step carbonization process, resulting in a homogeneous distribution of ZnO QDs within the mesostructured porous carbon. The composite showed high specific capacity and reversibility, making it a promising anode material for lithium ion batteries. Structural and morphological properties were thoroughly investigated using X-ray diffraction, scanning electron microscopy, and transmission electron microscopy.
Nanostructured ZnO materials have been studied extensively because of their functional properties. This paper presents a composite material of zinc oxide quantum dots (ZnO QDs) and porous carbon using a one-step carbonization process. The direct carbonization of a metal-organic complex generates mesostructured porous carbon with a homogeneous distribution of ZnO QDs. The structural and morphological properties are investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The resulting ZnO QDs@porous carbon composite delivers a high specific capacity of 990 mAh g(-1)at 100 mA g(-1), 357 mAh g(-1)at 2 A g(-1), and high reversibility when evaluated as an anode for lithium ion batteries.

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