Journal
NANO ENERGY
Volume 72, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.nanoen.2020.104708
Keywords
Small molecule; Self-organization; Alkyl side-chain; Organic photovoltaics; Perovskite solar cells
Categories
Funding
- National Research Foundation (NRF) [NRF-2015M1A2A2054029, 2015M1A2A2055631, 2019M3D1A2103995]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP) of the Republic of Korea [20173010012960, 20183010013820]
- National Research Foundation of Korea [2015M1A2A2055631, 2019M3D1A2103995] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The molecular self-organization of organic semiconductors, which is mainly determined by the structural design, film processing, and device configuration, is one of the crucial factors for achieving high-performance organic photovoltaics (OPVs) and perovskite solar cells (PvSCs). In this study, we newly synthesized and developed strongly self-organized small molecules via alkyl side-chain engineering. Replacing H to C6H13 on the thienyl group, SM2 showed a well-ordered face-on orientation. Due to favorable self-organization leading to effective charge carrier dynamics, including enhanced charge transfer/transport and suppressed recombination, SM2-based OPVs and PvSCs exhibited improved device performance compared to the devices based on SM1 without an additional hexyl side-chain. The best fullerene-based OPV and planar PvSC with SM2 as a small-molecule donor and as a hole transport layer (HTL) achieved an unprecedentedly high efficiency of 9.38% and 20.56%, in contrast with SM1-based devices showing lower efficiency of 8.70% and 15.37%. Furthermore, the planar PvSCs based on undoped-SM2 HTL exhibited comparable efficiency but provided excellent heat and humidity stability compared with doped spiro-OMeTAD-based devices. These results clearly indicated that SM2 with highly-ordered and favorable self-organization is a promising organic semiconductor for future applications of high-performance organic and inorganic-organic hybrid electronics.
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