Journal
ASIAN JOURNAL OF ORGANIC CHEMISTRY
Volume 9, Issue 10, Pages 1502-1518Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ajoc.202000341
Keywords
rhodium; quinolineN-oxide; transition metal catalysis; C-H activation
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Funding
- CSIR, New Delhi
- UGC, New Delhi
- CSIR [MLP0154/MLP0159]
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In the last two decades, rhodium-based catalysts have been used extensively for the sp(2)and sp(3)C-H bond activation/functionalization of various arenes, heteroarenes, and aliphatic compounds, respectively. For quinoline functionalization rhodium has been used significantly as compared to other transition metals such as cobalt, copper, ruthenium, palladium and iridium. In this Minireview the progress on rhodium-catalyzed selective functionalization of quinolineN-oxides and 8-methylquinolinesviasp(2)and sp(3)C-H bond activation, respectively have been highlighted. The main focus is on reaction mechanism, substrate scope, and positional selectivity.
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