4.6 Article

Facile synthesis of the magnetic BiOCl/ZnFe2O4 heterostructures with enhanced photocatalytic activity under visible-light irradiation

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.colsurfa.2016.08.066

Keywords

BiOCl/ZnFe2O4; Heterostructures; Hydrothermal; Visible-light region; PG

Funding

  1. National Natural Science Foundation of China [21107037, 21176107]
  2. National Postdoctoral Science Foundation [2013M530240]
  3. Postdoctoral Science Foundation [1202002B]
  4. Programs of Senior Talent Foundation of Jiangsu University [12JDG090]
  5. Key Scientific Programs of Higher Education of Henan Province of China [15A150069]
  6. Youth Foundation of Pingdingshan University [2012004]
  7. National Scientific Research Project Cultivating Foundation of Pingdingshan University [PXY-PYJJ2016005]

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The magnetic BiOCl/ZnFe2O4 heterostructures was successfully synthesized via a facile hydrothermal method and characterized by X-ray powder diffraction(XRD), scanning electron microscopy(SEM) and UV-vis diffuse reflectance spectroscopy. The results indicated that the new BiOCl/ZnFe2O4 composites exhibited wide absorption in the visible-light region. The heterostructures displayed exceptionally high photocatalytic activity (up to similar to 99%) compared with pure BiOCl (only to 43%) and ZnFe2O4 NPs (only to 27%) for the degradation of penicillin G (PG) under visible-light irradiation. Moreover, good recyclability was also obtained from the BiOCl/ZnFe2O4 photocatalysis. Meanwhile, A possible photocatalytic mechanism based on the BiOCl/ZnFe2O4 heterostructures has been proposed. (C) 2016 Elsevier B.V. All rights reserved.

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