Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 8, Issue 30, Pages 11069-11078Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c00249
Keywords
CoO/NiO nanosheets; polypyrrole nanotubes; peroxidase-like activity; colorimetric biosensing; ascorbic acid
Categories
Funding
- National Natural Science Foundation of China [51773075, 21875084]
- Project of Department of Science and Technology of Jilin Province, China [20190101013JH]
Ask authors/readers for more resources
Recently, hybrid biocatalysts with a unique interfacial structure have attracted significant attention for enzyme mimicking due to their superior catalytic activity compared with the single component catalyst. In this work, novel sheet-on-tube heterostructured polypyrrole (PPO@CoO/NiO nanotubes (NTs) are synthesized via an in situ growth strategy and are utilized for enzyme mimicking and sensing applications. The as-prepared PPy@CoO/NiO NTs can catalyze H2O2 into OH and realize the 3,3',5,5'-tetramethylbenzidine (TMB) oxidation, showing an excellent peroxidase-like property. Thanks to the synergistic effect between PPy NTs and CoO/NiO nanosheets, the catalytic performance of the resultant PPy@CoO/NiO NTs is superior to individual PPy NTs and bare CoO/NiO sheets as well as their physical mixture. In addition, the PPy@CoO/NiO NTs can also catalyze the H2O2 decomposing to generate O-2, possessing a catalase-like property. Then, we perform a simple visual method for sensitively detecting H2O2 and ascorbic acid (AA). This work demonstrates a distinctive route to promote the catalytic performance of enzyme-like nanomaterials for huge potentials in biotechnology and environment fields.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available