4.7 Article

Glycerolized Li+Ion Conducting Chitosan-Based Polymer Electrolyte for Energy Storage EDLC Device Applications with Relatively High Energy Density

Journal

POLYMERS
Volume 12, Issue 6, Pages -

Publisher

MDPI
DOI: 10.3390/polym12061433

Keywords

chitosan; glycerol plasticizer; electrical properties; impedance study; EDLC fabrication

Funding

  1. Ministry of Higher Education and Scientific Research-Kurdish National Research Council (KNRC), Kurdistan Regional Government/Iraq
  2. Prince Sultan University

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In this study, the solution casting method was employed to prepare plasticized polymer electrolytes of chitosan (CS):LiCO2CH3:Glycerol with electrochemical stability (1.8 V). The electrolyte studied in this current work could be established as new materials in the fabrication of EDLC with high specific capacitance and energy density. The system with high dielectric constant was also associated with high DC conductivity (5.19 x 10(-4)S/cm). The increase of the amorphous phase upon the addition of glycerol was observed from XRD results. The main charge carrier in the polymer electrolyte was ion ast(el)(0.044)

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