Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 646, Issue 13, Pages 964-967Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.202000037
Keywords
Chalcogenido metalate clusters; Tin; Sulfur; Non-innocent ionic liquids; Methylation
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Funding
- German Research Foundation (Deutsche Forschungsgemeinschaft, DFG) within the framework of the priority program SPP 1708 Materials Synthesis near Room Temperature
- German Research Foundation (Deutsche Forschungsgemeinschaft, DFG) within Graduate School Functionalization of Semiconductors [GRK 1708]
- Projekt DEAL
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A new salt of the alkylated oxo-thio stannate cluster [Sn10O4S16(SMe)(4)](4-), (C(4)C(4)C(1)Im)(4)[Sn10O4S16(SMe)(4)] (1), was obtained by ionothermal treatment of K-4[SnS4]center dot 4H(2)O. The reaction was carried out in the ionic liquid 1,3-dibutyl-2-methylimidazolium chloride, (C(4)C(4)C(1)Im)Cl, which proved to be non-innocent against the chalcogenido metallate species in the reaction mixture. In continuation of our first studies on alkylation of very weakly nucleophilic chalcogenido metalate anions, this study served to prove that an N-bonded alkyl group is selectively released from the imidazolium cation of the ionic liquid, and it served to show that methylation is favored over butylation. The title compound is one of the rare cases, in which the cations of the salt, which stem from the ionic liquid, could be crystallographically determined without problems.
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