Reductive Cross-Coupling of Vinyl Electrophiles

The synthesis of alkenes (olefins) is a central subject in the synthetic community. The transition-metal-catalyzed reductive cross-coupling of vinyl electrophiles has emerged as a promising tool to produce alkenes with improved flexibility, structural complexity, and functionality tolerance. In this review, we summarized the progress in this field with respect to cross-electrophile couplings and reductive Heck reactions using vinyl electrophiles. Introduction Cross-Electrophile Coupling of Vinyl Electrophiles Reductive Heck Reaction of Vinyl Electrophiles Summary and Outlook