4.5 Review

Carbonyl-Photoredox/Metal Dual Catalysis: Applications in Organic Synthesis

Journal

SYNTHESIS-STUTTGART
Volume 52, Issue 23, Pages 3493-3510

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707183

Keywords

dual catalysis; carbonyl-photocatalysis; transition-metal catalysis; C-C bond; C-O bond

Funding

  1. National Natural Science Foundation of China [21771131, 21971182]
  2. `Priority Academic Program Development' of Jiangsu Higher Education Institutions, Scientific and Technologic Infrastructure of Suzhou [SZS201708, SZS201905]

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Photoredox/metal dual catalysis is a versatile tandem methodology to construct carbon-carbon and carbon-heteroatom bonds. The focus of this short review is the application of this technology to C(sp(3))-C(sp(3)), C(sp(3))-C(sp(2)), C(sp(2))-C(sp(2)), C(sp(2))-O, and C(sp(3))-O bond formation induced by readily available and inexpensive carbonyl complexes as single electron transfer agents, photosensitizers, or hydrogen atom transfer agents.

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