4.5 Review

Recent Advances in Photocatalytic C-N Bond Coupling Reactions

Journal

SYNTHESIS-STUTTGART
Volume 52, Issue 20, Pages 2899-2921

Publisher

GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707136

Keywords

photochemistry; C-N cross-coupling; amination; radicals; visible light

Funding

  1. Research Grants Council, University Grants Committee (Hong Kong) [153037/14P, 153152/16P, 153023/17P, 153017/19P, C5023-14G]
  2. Hong Kong Polytechnic University, Department of Applied Biology and Chemical Technology
  3. State Key Laboratory for Chemical Biology and Drug Discovery (Hong Kong)

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Catalytic C-N bond formation is one of the major research topics in synthetic chemistry owing to the ubiquity of amino groups in natural products, synthetic intermediates and pharmaceutical agents. In parallel with well-established metal-catalyzed C-N bond coupling protocols, photocatalytic reactions have recently emerged as efficient and selective alternatives for the construction of C-N bonds. In this review, the progress made on photocatalytic C-N bond coupling reactions between 2012 and February 2020 is summarized.

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