Journal
SYNTHESIS-STUTTGART
Volume 53, Issue 1, Pages 123-134Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707232
Keywords
iodoperfluoroalkylation; frustrated Lewis pair; electron donor – acceptor complex; halogenations; radicals
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The article compares two metal-free catalytic iodoperfluoro-alkylation protocols, where frustrated Lewis pairs or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes and insights into the mechanistic details of both reaction pathways are provided.
A comparison of two catalytic, metal-free iodoperfluoro-alkylation protocols is presented. Frustrated Lewis pairs [ (t) Bu (3) P/B(C (6) F (5) ) (3) ] or phosphines/phosphites under visible light irradiation efficiently mediate the functionalization of non-activated alkenes and alkynes. A comprehensive account of the corresponding substrate scopes as well as insights into the mechanistic details of both reaction pathways are provided.
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