Journal
SYNLETT
Volume 31, Issue 18, Pages 1760-1774Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0040-1707156
Keywords
rhodium; fluoroolefins; C– H bond activation; C– F bond activation borylation; silylation; germylation; hydrodefluorination
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In this account we describe studies on the reactivity of rhodium(I) complexes of the type [Rh(E)(PEt3)3], where E represents hydrido, fluorido, germyl, boryl or silyl ligands, towards fluorinated olefins. The results are compared with those reported by other research groups on fluoroolefins, as well as with the chemistry of compounds [Rh(E)(PEt3)3] towards fluoroaromatics in terms of selectivity and mechanisms. 1 Introduction 2 Reactivity Towards Fluoroolefins 2.1 Reactivity of Hexafluoropropene 2.2 Reactivity of (E)-1,2,3,3,3-Pentafluoropropene 2.3 Reactivity of 2,3,3,3-Tetrafluoropropene and (E)-1,3,3,3-Tetrafluoropropene 2.4 Reactivity of 3,3,3-Trifluoropropene 2.5 Reactivity of Pentafluorostyrene 3 Conclusion and Perspective
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