4.7 Article

Spindle-like Fe2O3/ZnFe2O4 porous nanocomposites derived from metal-organic frameworks with excellent sensing performance towards triethylamine

Journal

SENSORS AND ACTUATORS B-CHEMICAL
Volume 317, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2020.128205

Keywords

MOF-derived; Fe2O3/ZnFe2O4 nanocomposite; Spindle; Porous; Heterojunction; Gas sensor

Funding

  1. National Natural Science Foundation of China [61102006, 51672110]
  2. Natural Science Foundation of Shandong Province, China [ZR2018LE006, ZR2015EM019]

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Recently, metal-organic frameworks (MOF)-derived porous metal oxide nanostructures have emerged as promising materials for gas-sensing detection. In this paper, MOF-derived Fe2O3/ZnFe2O4 porous nanocomposites were prepared successfully by a solvothermal method. The consequences of scanning electron microscope (SEM) and transmission electron microscope (TEM) exhibit the MOF-derived Fe2O3 spindles are uniform and adhered by ZnFe2O4 nanoparticles. Through the analyses of X-ray photoelectron spectroscopy (XPS) line fitting, the ZIF-8 has been translated into ZnFe2O4 on the surface of Fe2O3 spindles after calcination process and the specific surface area of Fe2O3/ZnFe2O4 nanocomposites is 41.7 m(2)/g, which is beneficial for the gas diffusion. With respect to the gas sensing text, the sensing performance of Fe2O3/ZnFe2O4 nanocomposites is superior to pure Fe2O3 spindles. Particularly, gas sensors prepared by Fe2O3/ZnFe2O4 nanocomposites can detect 200 ppb triethylamine (TEA) and the value of sensing response is 2.44. Therefore, the MOF-derived Fe2O3/ZnFe2O4 nanocomposite is a promising sensing material.

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