Benzotriazoles and benzothiazoles prevail in indoor dust from an E-waste dismantling area in South China: Elevated concentrations and implication for human exposure

In this study, 6 BTRs and 9 BTHs were detected in indoor dust samples collected from a typical e-waste dismantling area and adjacent residential areas, as well as from a control urban area. The median Sigma BTRs (the total concentrations of BTRs) in e-waste dismantling workshop dust (3830 ng/g) was up to about 21 and 17 times higher than those in the local residential house dust (180 ng/g) and the control urban residential house dust (231 ng/g), respectively. Similarly, significantly higher Sigma BTHs (the total concentrations of BTHs) were also found in indoor dust from e-waste workshops (median: 2070 ng/g; range: 590-4430 ng/g) compared to the local residential houses (823 ng/g; 268-3350 ng/g) and the control urban residential houses (930 ng/g; 400-3650 ng/g). These results indicate that e-waste dismantling activities contribute to considerable residues of BTRs and BTHs in indoor dust. Benzotriazole (BTR), benzothiazole (BTH) and 2-hydroxy-benzothiazole (2-OH-BTH) were identified as the predominant compounds across three types of dust samples, cumulatively representing over 80% of Sigma BTs (the sum of Sigma BTRs and Sigma BTHs). The different applications of BTRs and BTHs in e-products were clarified based on correlations analysis. The estimated daily intakes (EDIs) of BTRs and BTHs through dust intake for occupational workers were much higher than those for local and urban residents, implying that a potentially high risk can be posed to occupational workers. (c) 2020 Elsevier B.V. All rights reserved.