4.5 Article

A green solid acid catalyst 12-tungstophosphoric acid H3[PW12O40] supported on g-C3N4for synthesis of quinoxalines

Journal

RESEARCH ON CHEMICAL INTERMEDIATES
Volume 46, Issue 9, Pages 4193-4209

Publisher

SPRINGER
DOI: 10.1007/s11164-020-04200-0

Keywords

Heteropoly acid; Graphitic carbon nitride; Solid acid catalyst; Quinoxalines; Water as solvent

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A green Keggin-type heteropoly-12-tungstophosphoric acid, (H-3[PW12O40].12H(2)O) supported on graphitic carbon nitride g-C3N4(HPW/g-C3N4-40), was developed for one-pot synthesis of quinoxaline derivatives from 1,2-diketone and 1,2-diamines. Use of green solvent, heterogeneous reaction condition, simple workup procedure, short reaction time and reusability of the catalyst are the advantages of this protocol.

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