Journal
PURE AND APPLIED CHEMISTRY
Volume 92, Issue 8, Pages 1181-1199Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/pac-2020-0301
Keywords
adamantane; amination; click reactions; Cu catalysis; immobilization; Mendeleev-21; polyamines; Steroids
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Funding
- Russian Foundation for Basic Research [17-03-00888]
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A mini-review describes the development of the catalysis by Cu(I) complexes aimed at the formation of C-N bond at the Lomonosov MSU during 2010s. The main approach employs the amination of aryl and heteroaryl halides with the amines and polyamines, in this direction a great versatility of starting compounds was achieved: adamantane-containing amines, linear diamines, oxadiamines and polyamines, various aryl iodides and bromides, derivatives of pyridine, and quinoline were used for this purpose. In more peculiar cases, the copper catalysis was used for steroids transformations, including vinylation of azoles, wide-spread click reactions for the conjugate syntheses, and successful heterogenezation of the copper catalysts were also undertaken.
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