Journal
POLYMER
Volume 203, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2020.122765
Keywords
Polymer dielectrics; Dipolar glass polymer; Dielectric constant; Loss tangent; Broadband dielectric spectroscopy; Energy storage
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Funding
- CONICYT [21150512]
- Universidad Mayor
- Fondecyt [1161159]
- FON-DAP [15110019]
- Basque Country Government [GIU18/216]
- spanish Ministerio de Economia y Competitividad [PGC2018-097699-B-I00]
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This work introduces, for the first time, the dipolar glass copolymer concept as a new strategy to develop polymer dielectrics. Methacrylic monomers containing sulfone and nitrile groups were copolymerized with N-vinyl-2-pyrrolidone, achieving the preparation of 9 new copolymers with higher dielectric properties than conventional polymer dielectrics. These copolymers, besides exhibiting dielectric constant values between 5.3 and 8.2 and dissipation factors below 0.022, compared to their respective poly(methacrylate) homopolymers, exhibit higher T-g values allowing to delay, on the temperature scale, the occurrence of highly dissipative phenomena (e.g. a relaxation and ionic conductivity). Therefore, these new dipolar glass copolymers can be considered as polymers with high dielectric constants, reasonably low loss values and broader working temperature ranges than conventional polymers dielectrics. Finally, results presented in this work reveal the significant effect that dipolar interactions within the material could have on the dielectric properties of these systems, opening a new research line based on the design of new dipolar glass copolymers with outstanding dielectric performance.
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