Journal
ORGANOMETALLICS
Volume 39, Issue 13, Pages 2464-2469Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00261
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Funding
- Cooperative Research Program of the Network Joint Research Center for Materials and Devices
- JSPS KAKENHI from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan [16H0412100]
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A series of new palladium complexes containing a Cu(I) photosensitizing unit were synthesized in good yields by the reaction of [(bpm)Pd(CH3)(solv.)](+) (bpm = 2,2'-bipyrimidine) complex with Cu(I) precursors. One of the CuPd dinuclear complexes was structurally characterized by single-crystal X-ray diffraction and showed sterically congested Cu center. The CuPd complexes catalyzed styrene polymerization under visible-light irradiation to furnish polystyrenes via a nonradical mechanism.
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