Journal
ORGANOMETALLICS
Volume 39, Issue 14, Pages 2565-2569Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.0c00294
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Funding
- Japan Society for the Promotion of Science [17H03029]
- Dynamic Alliance for Open Innovation Bridging from the Ministry of Education, Culture, Sports, Science and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [17H03029] Funding Source: KAKEN
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The gold(I) thiolate complex [Au(SC6H4-4-OMe)-(PCy3)] reacts with an (aminosilyl)boronic ester, Et2N-SiPh2-BO(CMe2)(2)O, to afford a complex with an (arylthio)silyl [Au(SiPh2(SC6H4-4-OMe))(PCy3)]. In the solid state the molecule shows almost linear Si-Au-I-P coordination. DFT studies revealed that the reaction pathway involves an intermediate having an Au-S bond formed via initial association of the Si center of the substrate with the thiolate ligand. Reaction of H2SiPh2 with the thiolate complex also produces the silylgold complex in a lower yield.
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