Journal
ORGANIC LETTERS
Volume 22, Issue 15, Pages 5968-5972Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02068
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Funding
- German Science Foundation (DFG) [Hi655 -GRK 2226]
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The electrochemical, oxidative Umpolung reaction of silyl enol ethers utilizing simple iodide salts for the synthesis of alpha-amino ketones is described. The products were isolated in excellent yields of up to 100%, and various functionalized starting materials were accepted in an undivided electrochemical cell design. Moreover, a sensitivity assessment to ensure an improved reproducibility of the reaction and cyclic voltammetry experiments were performed to postulate a plausible reaction mechanism on their basis.
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