Journal
ORGANIC LETTERS
Volume 22, Issue 16, Pages 6584-6589Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02352
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Funding
- CNRS
- University Paris-Sud
- ANR [ANR-15-CE29-0002]
- la Ligue Contre le Cancer through an Equipe Labellisee 2014 grant
- China Scholarship Council
- Agence Nationale de la Recherche (ANR) [ANR-15-CE29-0002] Funding Source: Agence Nationale de la Recherche (ANR)
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A general protocol for functionalization of an anomeric selonate anion at room temperature has been reported. By using the PdG3 XantPhos catalyst, the cross-coupling between the in situ generated glycosyl selenolate and a broad range of (hetero)aryl and alkenyl iodides furnished a series of functionalized selenoglycosides in excellent yields with perfect control of the anomeric configuration.
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