Journal
ORGANIC LETTERS
Volume 22, Issue 13, Pages 5140-5144Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01744
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Funding
- NSF of China [21572072]
- Xiamen Southern Oceanographic Center [15PYY052SF01]
- 111 project [BC2018061]
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An efficient and regioselective synthesis of fused polycyclic furo[3,4-c]indolo[2,1-a]isoquinolines through Rh(III)-catalyzed cascade C-H activation/annulation/lactonization of 2-arylindoles and 4-hydroxy-2-alkynoates has been developed. This cascade reaction displays high step economy and efficiency and tolerates various functional groups. The titled polycyclic furo[3,4-c]indolo[2,1-a]isoquinolines exhibit fluorescence emission.
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