Journal
ORGANIC LETTERS
Volume 22, Issue 16, Pages 6288-6293Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c02053
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Funding
- National Natural Science Foundation of China [21772075, 21532001]
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A novel visible-light-induced palladium-catalyzed Heck reaction for bromine sugars and aryl olefins with high regioand stereochemistry selectivity for the preparation of C-glycosyl styrene is described. This reaction takes place in one step at room temperature by using a simple and readily available starting material. This protocol can be scaled up to a wide range of glycosyl bromide donors and aryl olefin substrates. Mechanistic studies indicate that a radical addition pathway is involved.
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