Journal
ORGANIC LETTERS
Volume 22, Issue 14, Pages 5347-5352Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01592
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Funding
- National Natural Science Foundation of China [21772183]
- Fundamental Research Funds for the Central Universities [WK2060190086]
- 1000-Youth Talents Plan start-up funding
- University of Science and Technology of China
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Herein we successfully applied Katritzky salts as the alkyl electrophile in the reductive allylic defluorinative cross-coupling reaction with alpha-trifluoromethyl alkenes. The merger of C-F and C-N bond cleavage via the synergistic effect of nickel and zinc allows the efficient synthesis of diverse gem-difluor-oalkenes with a good tolerance for various functional groups.
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