Journal
ORGANIC LETTERS
Volume 22, Issue 14, Pages 5605-5609Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01973
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Funding
- CSIR, New Delhi [02(0307)/17/EMR-II]
- CSIR
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A general and practical method for the direct C-H amination of 2H-indazoles with a series of amines including aliphatic primary amines, secondary amines, azoles, and sulfoximines via organophotoredox-catalyzed oxidative coupling has been disclosed at room temperature under ambient air conditions. Additionally, this protocol is used for free aminated 2H-indazole synthesis. A mechanistic study revealed that a single electron transfer (SET) pathway might be involved in this reaction.
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