Journal
ORGANIC LETTERS
Volume 22, Issue 12, Pages 4781-4785Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.0c01580
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Funding
- National Key Research and Development Program of China [2016YFA0602900]
- National Natural Science Foundation of China [21971071]
- foundation of the Department of Education of Guangdong Province [2017KZDXM085]
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Herein, we present a ruthenium-catalyzed new hydrogen evolution ortho-aminoalkylation of phenolic derivatives with cyclic amines as the coupling agents. The developed cross-coupling reaction offers a practical platform for direct access to a variety of functionalized phenols with the features of good substrate and functional group compatibility, readily available catalyst system and feedstocks, no need for additional sacrificial oxidants, and high atom efficiency.
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