Interfacial engineering of Ni/V2O3for hydrogen evolution reaction

Electrocatalytic water splitting offers a sustainable route for hydrogen production, enabling the clean and renewable alternative energy system of hydrogen economy. The scarcity and high-cost of platinum-group-metal (PGM) materials urge the exploration of high-performance non-PGM electrocatalysts. Herein, a unique hierarchical structure of Ni/V(2)O(3)with extraordinary electrocatalytic performance (e.g., overpotentials as low as 22 mV at 20 mA center dot cm(-2)and 94 mV at 100 mA center dot cm(-2)) toward hydrogen evolution reaction in alkaline electrolyte (1 M KOH) is reported. The investigation on the hierarchical Ni/V(2)O(3)with a bimodal size-distribution also offers insight of interfacial engineering that only proper Ni/V(2)O(3)interface can effectively improve H2O adsorption, H2O dissociation as well as H adsorption, for an efficient hydrogen production.