Journal
MOLECULES
Volume 25, Issue 14, Pages -Publisher
MDPI
DOI: 10.3390/molecules25143311
Keywords
confinement; solid-state NMR; molecular dynamics; interfaces and surfaces
Funding
- Deutsche Forschungsgemeinschaft [FOR 1583, Bu-911/18-1/2, Vo-905/8-1/2, Vo-905/9-1/2, Vo-905/10-1/2]
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This review gives an overview of current trends in the investigation of small guest molecules, confined in neat and functionalized mesoporous silica materials by a combination of solid-state NMR and relaxometry with other physico-chemical techniques. The reported guest molecules are water, small alcohols, and carbonic acids, small aromatic and heteroaromatic molecules, ionic liquids, and surfactants. They are taken as characteristic role-models, which are representatives for the typical classes of organic molecules. It is shown that this combination delivers unique insights into the structure, arrangement, dynamics, guest-host interactions, and the binding sites in these confined systems, and is probably the most powerful analytical technique to probe these systems.
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