Determination of Cadmium (II) in Aqueous Solutions by In Situ MID-FTIR-PLS Analysis Using a Polymer Inclusion Membrane-Based Sensor: First Considerations

Environmental monitoring is one of the most dynamically developing branches of chemical analysis. In this area, the use of multidimensional techniques and methods is encouraged to allow reliable determinations of metal ions with portable equipment for in-field applications. In this regard, this study presents, for the first time, the capabilities of a polymer inclusion membrane (PIM) sensor to perform cadmium (II) determination in aqueous solutions by in situ visible (VIS) and Mid- Fourier transform infrared spectroscopy (MID-FTIR) analyses of the polymeric films, using a partial least squares (PLS) chemometric approach. The influence of pH and metal content on cadmium (II) extraction, the characterization of its extraction in terms of the adsorption isotherm, enrichment factor and extraction equilibrium were studied. The PLS chemometric algorithm was applied to the spectral data to establish the relationship between cadmium (II) content in the membrane and the absorption spectra. Furthermore, the developed MID-FTIR method was validated through the determination of the figures of merit (accuracy, linearity, sensitivity, analytical sensitivity, minimum discernible concentration difference, mean selectivity, and limits of detection and quantitation). Results showed reliable calibration curves denoting systems' potentiality. Comparable results were obtained in the analysis of real samples (tap, bottle, and pier water) between the new MID-FTIR-PLS PIM based-sensor and F-AAS.