4.7 Article

Frozen-State Polymerization as a Tool in Conductivity Enhancement of Polypyrrole

Journal

MACROMOLECULAR RAPID COMMUNICATIONS
Volume 41, Issue 17, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/marc.202000364

Keywords

conducting polymers; frozen polymerization; organic dyes; polypyrrole

Funding

  1. Czech Science Foundation [18-04669S]

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Polypyrrole (PPy) is oxidatively polymerized in the frozen state at -24 degrees C in the presence of various organic dyes as morphology guiding agents in order to form homogeneous 1D PPy nanoforms. The freezing polymerization of pyrrole has a significant influence on the electrical conductivity and thermal stability but negligible influence on the yield compared to widely used room temperature polymerization.

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