Journal
JOURNAL OF THE JAPAN PETROLEUM INSTITUTE
Volume 63, Issue 4, Pages 221-227Publisher
JAPAN PETROLEUM INST
DOI: 10.1627/jpi.63.221
Keywords
Lignin depolymerization; Aromatic monomer; Supercritical water; Supported metal catalyst; Organosolv-lignin
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Funding
- Japan Society for the Promotion of Science (JSPS) KAKENHI [JP17H00803]
- Japan Association of Chemical Innovation (JACI) through the New Chemical Technology Research Encouragement Award, Step-Up Award
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Lignin is a potentially useful source of aromatic monomers. Depolymerization of organosolv-lignin into aromatic monomers was investigated over charcoal-supported palladium, platinum, rhodium, or ruthenium catalyst (Pd/C, Pt/C, Rh/C, and Ru/C) in supercritical water (658-688 K) for reaction times of 0.5-3 h. Ru/C showed no catalytic activity for lignin depolymerization into aromatic monomers, but did catalyze conversion of lignin into gaseous products such as methane and carbon dioxide. In contrast, Pd/C, Pt/C, and Rh/C showed catalytic activity for lignin depolymerization into aromatic monomers. Yield of aromatic monomers decreased in the order Pd/C > Rh/C > Pt/C at 673 K and 1 h. Pd/C showed higher selectivity for phenolic aromatic monomers than Rh/C and Pt/C. Investigation of the activity of Pd/C at 673 K over time (0.5-3 h) found the highest yield of aromatic monomers (12.7 %) was obtained at 2 h.
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