Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 11, Issue 16, Pages 6487-6491Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.0c01953
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Funding
- PAPIIT [IN222819]
- PAIP
- CONACYT
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We report herein a molecular engineering strategy based on the design of a multipolar ruthenium-nitrosyl (Ru-NO) complex with a three-branched architecture. The three Ru-NO units are introduced at the periphery of a highly pi-delocalized truxene core bearing three terpyridine ligands. The two-photon absorption capabilities of the complex were investigated by the Z-scan technique. The strong electronic coupling among the individual arms gives rise to a very strong two-photon absorption response (delta(800 nm) similar to 1600 GM), which corresponds to a 16-fold enhancement of the capability of a single-arm reference, thereby promoting an efficient light-driven NO release process in aqueous media.
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