Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 925, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2020.121468
Keywords
Amines; Carbon monoxide; Hydridotris(pyrazolyl)borate complexes; Reductive amination; Rhodium
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Funding
- Russian Science Foundation [19-73-20212]
- Ministry of Science and Higher Education of the Russian Federation
- Russian Science Foundation [19-73-20212] Funding Source: Russian Science Foundation
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The halide complexes TpRhCl(2)(MeOH) and Tp(Me2)RhI(2)(CO) (Tp = hydrotris-(pyrazolyl)borate; Tp(Me2) = hydrotris-(3,5-dimethylpyrazolyl)borate) were synthesized by reactions of RhCl3 with K[Tp] in methanol and Tp(Me2)Rh(CO)(2) with iodine, respectively. Reactions of Tp(Me2) RhCl2(MeOH) and Tp(Me2)RhI(2)(CO) with 1,10-phenanthroline afford the phenanthroline derivatives [Tp(Me2)Rh(phen)X](+) (X = Cl, I). The structures of TpRhCl(2)(MeOH) and TpRhI(2)(CO) were determined by X-ray diffraction. Tris(pyrazolyl)borate rhodium complexes effectively catalyze the reductive amination and the reductive esterification of aldehydes in the presence of carbon monoxide. (C) 2020 Elsevier B.V. All rights reserved.
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