Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1214, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2020.128213
Keywords
1,3-Dipolar cycloaddition; Pyrazoline; Photophysical properties; Solute-solvent interactions; Kamlet-taft and Catalan parameters
Categories
Funding
- [FBG-2018-6476]
- [FAD-2019-7025]
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New (4S*,5S*)-Methyl 3-(2,3-dimethoxyphenyl)-5-(3,4-dimethoxyphenyl)-1-phenyl-4,5-dihydro-1H-pyrazole-4-carboxylate (4) and its isomer 5 were synthesized from 1,3-dipolar cycloaddition reaction of a hydrazonyl chloride with a cinnamic acid derivative and solvent effects on absorption and fluorescence properties of the novel synthesized pyrazoline derivatives (isomers 4 and 5) were studied by UV-Vis. absorption and steady-state fluorescence spectroscopy techniques. The absorption and fluorescence spectra for both isomers showed that solvent structure and polarity have effect on photophsical properties of the isomer molecules. Isomers 4 and 5 exhibited positive solvatochromism behavior when the polarity of the solvent was increased from p-Xylene to MeOH. Furthermore, isomers 4 and 5 showed very high quantum yields in the solvents except for polar solvents and bromobenzene. Solute-solvent interactions were analyzed by using the solvent polarity parameter (E-T(30)) approach, Lippert-Mataga equation, Kamlet-Taft and Catalan multiple linear regression analysis. These results revealed that the most contributing factor of solute-solvents interactions for the isomer 4 was the solvent acidity whereas the most contributing factors for isomer 5 was the solvent acidity as well as the solvent polarity. (C) 2020 Elsevier B.V. All rights reserved.
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