Journal
JOURNAL OF MOLECULAR LIQUIDS
Volume 319, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molliq.2020.113935
Keywords
Mixing enthalpy; Thulium(III) chloride; Lithium chloride; Sodium chloride; Potassium chloride; Rubidium chloride
Funding
- Polish Ministry of Science and Higher Education for the Faculty of Chemistry of Wroclaw University of Science and Technology
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The molar enthalpies of mixing (Delta H-mix(m)) in the liquid alkali chloridethulium (III) chloride mixtures have been measured with a Calvet-type high temperature microcalorimeter over the entire composition range at 1130 K. Mixing of the two liquid components was achieved by using the break-off ampoule technique. All the melts are characterized by negative enthalpies of mixing with a minimum value of approximately: 1.8, 10.3, 23.4, and 26.0 kJ . mol(-1), for systems with LiCl, NaCl, KCl and RbCl, respectively. For all systems, the minimum of the enthalpy of mixing is shifted towards the alkali chloride-rich compositions and located in the vicinity of x(TmCl3) similar to 0.350. The composition dependence of the interaction parameter lambda, with a broad minimum at x(TmCl3) similar to 0.2 for all of the systems is indicative of TmCl63- complexes formation in the melts. The results were discussed with using Papatheocloru-Ostvold model of complexes formation and Associate Solution Model. The configurational mixing entropy of investigated systems has been calculated and commented. (C) 2020 The Authors. Published by Elsevier B.V.
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