Journal
JOURNAL OF CLUSTER SCIENCE
Volume 32, Issue 3, Pages 613-620Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10876-020-01820-9
Keywords
Polyoxoniobate; Trivalent nickel complex; Reactive oxygen species; Crystal structure analysis; Lindqvist-type cluster; Nanoscale
Categories
Funding
- Natural Science Foundation of China [21573056]
- Shanxi Province Science Foundation for Youths [201901D211453]
- Research Foundation for Advanced Talents of Shanxi Province [1800008001]
- Research Foundation of Taiyuan Institute of Technology [03000352]
- Research Foundation of the Chinese State Key Laboratory of Coordination Chemistry [SKLCC1912]
Ask authors/readers for more resources
A nanoscale polyoxoniobate, NEN, based on trivalent nickel complex and Lindqvist-type cluster has been synthesized and shown to efficiently catalyze the production of reactive oxygen species in aqueous solution system.
A nanoscale polyoxoniobate based on trivalent nickel complex and Lindqvist-type cluster, [Ni(en)(3)](2)[H2Nb6O19]center dot 8H(2)O (abbreviated as NEN) (en = ethylenediamine, C2H8N2) has been synthesized and structurally characterized by elemental analyses, IR spectrum, UV-visible spectra, X-ray photoelectron spectrum (XPS), thermogravimetric analysis (TGA) and single-crystal X-ray diffraction. Structural analysis shows that NEN is an ionic compound, in which the cations are two trivalent nickel complexes [Ni(en)(3)](3+) and the anion is a Lindqvist-type polyoxoniobate [Nb6O19](8-) cluster. Notably, NEN can catalyze the production of reactive oxygen species efficiently in aqueous solution system.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
