Journal
JOURNAL OF CATALYSIS
Volume 386, Issue -, Pages 19-29Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2020.03.024
Keywords
Oleic acid; HDO pathway; Phosphoric acid - MIL-101Cr; Pt-based catalyst; Solvent double method
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2017R1A2B4007648]
- C1 Gas Refinery Program through the National Research Foundation of Korea (NRF) - Ministry of Science and ICT [2015M3D3A1A01064882]
- National Research Foundation of Korea [2017R1A2B4007648] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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The Pt-doped H3PO4@MIL-101Cr catalysts, with a series of phosphoric acid concentrations, were successfully synthesized using the double-solvent method for efficient hydrodeoxygenation (HDO) of fatty acid. The phosphoric acid modification of 1%Pt/MIL-101 enhanced the catalytic performance of HDO conversion of oleic acid in the gas phase with a 1.5-11 times higher turnover frequency (TOF) over metal site compared to the original Pt/MIL-101 catalyst. Moreover, the increase in the number of the moderate acid sites facilitates the decarbonylation/carboxylation compared to the hydrodeoxygenation reaction, based on the gradual increase in the ratio of nC(17)/nC(18) due to the significant increase of the moderated Bronsted acid site. The FE-TEM and CO chemisorption measurements demonstrated that the Pt nanoparticles were highly dispersed on the support, and that they shifted to a larger size distribution due to the competitive adsorption between the acid site and metal site, with diameters in the range of 1.72-3.89 nm. The catalytic stability of a phosphoric acid modified-catalyst was maintained above 75% for 24 h of the HDO reaction. The application of phosphoric acid - MOF-based catalysts for the HDO of a model fatty acid compound was demonstrated for the first time, to the best of our knowledge, exhibiting an efficient catalyst system for HDO in a gas-phase process. (C) 2020 Elsevier Inc. All rights reserved.
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