4.7 Article

Three-dimensional multi-phase simulation of PEM fuel cell considering the full morphology of metal foam flow field

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 46, Issue 3, Pages 2978-2989

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.05.263

Keywords

PEM fuel Cell; Metal foam; Full morphology; 3D; Multi-phase simulation

Funding

  1. China-UK International Cooperation and Exchange Project (Newton Advanced Fellowship)
  2. National Natural Science Foundation of China [51861130359]
  3. UK Royal Society [NAFyR1y180146]
  4. National Natural Science Foundation of Tianjin (China) for Distinguished Young Scholars [18JCJQJC46700]

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The study investigates the influence of a metal foam flow field on transport phenomena and electrochemical reactions in PEM fuel cells using a 3D multi-phase non-isothermal model. Results show that the metal foam design greatly increases fuel cell performance and leads to more uniform distributions of oxygen and current density compared to conventional flow fields.
It is well-known that flow field design is of primary importance to optimization of proton exchange membrane (PEM) fuel cell. Traditional channel-rib flow fields, e.g. parallel or serpentine channels, always lead to non-uniform distributions of reactant gas, liquid, current density and so on between the channel and rib regions. Metal foam materials with high porosity (>90%) have been proposed as alternative flow fields for PEM fuel cells. In this study, influences of metal foam flow field on the transport phenomena coupled with the electrochemical reactions in PEM fuel cell are investigated using a three-dimensional (3D) multi-phase non-isothermal model. Specifically, the full morphology of metal foam flow field is taken into account in the 3D simulation after validated against experimental permeability data. The full morphology inclusion enables capture of the detailed gas flow from the flow field into the gas diffusion layer (GDL) and the current collection at the metal foam/GDL interface. In addition, compared with the conventional channel-rib flow fields, the metal foam design greatly increases fuel cell performance in the high current density regime. In addition, the oxygen and current density distributions in PEM fuel cell with the metal foam flow field are more uniform than those in the conventional one. Though the current collection area at the GDL surface is much smaller in the metal foam flow field, the relevant Ohmic loss won't increase significantly due to the improved physical contact by the fine pore structure of metal foam over the GDL. (c) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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