Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 45, Issue 46, Pages 24765-24778Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2020.06.255
Keywords
Reorganization; Carbo-benzene dye; Silver nanoparticles; Titanium dioxide nanoparticles; Triptych material; Photocatalytic hydrogen production
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Funding
- Centre National de la Recherche Scientifique CNRS (PhotoH2 prematuration project)
- Universite de Toulouse (IDEX MUSE project)
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The preparation of a triptych nanomaterial made of TiO2 nanoparticles as semiconductor, Ag plasmonic nanoparticles and a carbo-benzene macrocyclic molecule as photosensitizer is described, and used to produce hydrogen by photo-reduction of pure deionized water under 2.2 bar argon pressure without any electrical input. Silver nanoparticles (similar to 5 nm) are grafted onto the surface of commercial TiO2 nanoparticles (similar to 23 nm) by a photo-deposition process using an original silver amidinate precursor. The thickness of the photosensitive layer (2 nm), which completes the assembly, plays a crucial role in the efficiency and robustness of the triptych nanocatalyst. Thanks to the organic layer reorganization during the first similar to 24 h of irradiation, it leads to an enhancement of the hydrogen production rate up to 5 times. The amount of silver and carbo-benzene are optimized, along with the mass concentration of nanocatalyst in water and the pH of the aqueous medium, to allow reaching a hydrogen production rate of 22.1 mu mol.h(-1).g(photocatalyst)(-1) . (C) 2020 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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